He had a little extra power which was fine because that was the premise of the fic.īut then the rune etching began. The first few chapters made some very bold moves that subverted a few expectations like Killing off Hermione and having a "brilliant scheme" backfire ending up in Dobby's death and dealing with those events in a realistic way which I respected. I really enjoyed the start of linkffn(For Love of magic). Bot replies too long? Recommending many fics? Add ffnbot!slim to your comment for more compact bot replies.Want to recommend a thread? linksub(thread_id) or linksub(thread_url) (works with hyperlinks, too!).Edited your comment? Bot reply not there? Reply to it with ffnbot!refresh to re-link fics.Link multiple fics by using semicolons: linkffn(Emperor Wit of the Raven).linkffn(Emperor by Marquis Black)) will almost always work, linking by fic ID or URL (eg. linkffn(Emperor)), using fic title and author (eg. Linking by fic title will usually work (eg.Submit Book Club Recommendation BOT USAGEĪdult FanFiction - linkaff(story URL only) HP Fanfiction related subreddits may be linked to as long as the content is not being spammed. This includes but is not limited to discords, merchandise, paid applications, paid promotions etc. This applies to all posts, including Discussions, and Request Threads. If a topic is not to your taste, use language that makes it clear it is your opinion while not attacking people. ![]() Be respectful of other users' likes and preferences when posting. Gratuitous or positive depictions of non-consensual sexual content are also subject to removal. ![]() All direct links to such content will be removed. Please note reddit's policy regarding this issue. No direct links to sexual or suggestive content involving minors. ![]() "What's that fic?" is for finding a specific fic. Request threads are for recommendations of a certain critera. Pretending to be an author and making comments on an authors' behalf will not be tolerated.ĭo not use this subreddit to try to circumvent the rules of other fanfiction communities or the will of authors. Purposefully inciting arguments, personal attacks and threats will not be tolerated. Homophobia, transphobia, sexism, racism or any other derogatory language will not be tolerated. How to flair your post Search For Posts By Flair! This is the official r/hpfanfiction Discord Server!
0 Comments
![]() ![]() We may cancel or change this offer or cancel your order without notice due to insufficient supply, your noncompliance with offer terms, lack of bank authorization, system error, unforeseen problems, or for any other reason. NOT COMBINABLE WITH any other promotion, sale, discount, outlet item, or discounted value or gift set.Īpplicable purchase amount does not include items not in stock at time of purchase, items not designated for the offer, pending purchases, or purchases made before or after the offer period, or any offer fees or costs, such as cost of shipping, handling, and sales tax. Customer may choose only one gift to redeem. ![]() Purchases from our offline store do not qualify. Offer: Available to residents of the U.S. Gift includes: microdelivery cleanser 30ml, microdelivery dream peel 1.5ml, purity made simple cleanser 30ml, ultimate miracle worker moisturizer spf30 7ml, hope in a jar smooth glow moisturizer 7ml, dose of wisdom bouncy skin reactivating serum 3ml, pouch. Offer valid from August 5 (12:00 AM PDT) to August 14 (11:59 PM PDT), 2023. Enjoy a 7-piece gift with your purchase of $60 or more on .Īdd purchase to cart and select gift at checkout to redeem. If only there was an internationally recognized sound that alleviates stress, brings laughter, lowers blood pressure, clears a room, helps bring peace to the middle east and is enjoyed by both Democrats and Republicans. You can also record and rename multiple farts which are stored in the FAVES list. Using our FAVES feature you can create a playlist of your fave farts for easy access. Using iFart’s "Record-A-Fart" feature you can now make audible memories for a lifetime and play them for friends and family. The birth of a child, a stunning sunset, bigfoot, and of course, the after effects of a triple burrito lunch. There are special moments in life that just have to be captured on your phone to be believed. ![]() When the Sneak Attack goes off, slip away or take out the bad guys when they reach for their noses. Then place your phone in a strategic location and move silently away. Simply pull out your phone, choose a sound effect and set the timer up to 30 seconds. Bad guys are closing in on you, but if you only had a distraction, you could escape. Let's say that you're in a warehouse gun battle. The sneak attack function can literally save your life. Most criminals know how to lie, but "it wasn't me" isn't going to work with iFart.Ĭall the authorities and send these phone stealing scumbags off to the gas chamber. Phones and pdas are stolen on a daily basis, but if you are using iFart's advanced security system you can stop criminals right in their tracks.Īnd when thieves try to snatch your phone, they'll be in for a shock when they're blasted by your chosen sound effect. Here are just a few of the useful, signature features of iFart®. The App has been completely recoded and rebuilt for 2021. We can’t even tell you how much time it spent farting around at #2. ![]() It continued to linger in the Top Ten for over a year! ![]() It blasted to #1 on Christmas Day of that year and clinged to number one for weeks. IFart® took the app world by storm in 2008. The definitive Fart Sounds app on iTunes.įeatured on The Daily Show with Jon Stewart, The Today Show and many others, iFart® is considered the most infamous app of all time.Īlso seen in the Wall Street Journal, USA Today,, MacDailyNews, MacForums, The New York Times, Barron's, Motley Fool, Gizmodo, Venture Beat, Ars Technica, CNET News,, Forbes, The UK Register, Information Week, and dozens of publications all over the world! You’ve discovered the Original and World Famous iFart® App. ![]() Even in the case of other players using the enticing bling aids, I still enjoy the simple pleasure of mixing letters with the use of my own brain and it matters not if other players do or do not. not just demanding a higher target every week making it sometimes too difficult to achieve it in the time I allow myself to play. I enjoy the badges and find myself trying to achieve the set goal, however, I wish those weekly goals would scramble from high to low, low to high, and everywhere in between. I play with like-minded players (I think!) and play just for the sheer fun of building words! A wordsmith at heart I suppose. and have played it for years every morning with my morning cup of coffee…I play the old-fashioned way with none of the colorful play options perched above for the less astute player. Just another title from Zynga’s Games With Friends™ “The game is free to play however, in-app purchases are available for additional content and in-game currency.” Up-to-date on game news, contests, polls and more.įor more information, see our Terms of Service: and Privacy Policy: " Be sure to login with Facebook or the email account you used to make the previous purchase to continue to play without third party ads between moves.Īlready an accomplished Wordie? Like us on Facebook or follow us on Twitter to stay *Play Words With Friends without third party ads between moves if you previously purchased Words With Friends Pro on iOS or any other mobile device. 6 LANGUAGES: Choose to play in Spanish, French, German, Italian, Brazilian Portuguese and British English.SMART MATCH: Connect with players of a similar skill with Smart Match.PROFILE FRAMES: Show off your unique style with custom profile frames.WORD RADAR: Heat map reveals the location of all possible moves before you take a turn.HINDSIGHT: Uncover the best word you could have played after each turn.SOLO PLAY: Play offline and sharpen your skills with solo play.BEAT THE CLOCK: Challenge friends to beat the clock in fast play!.WEEKLY CHALLENGE: Play the weekly challenge and earn fun, themed badges.Test your brain power and spell your way to victory. Words With Friends is the fun, free word game that lets you connect with friends and family while expanding your vocabulary and sharpening your wit. Good luck in your next word game! With these tips we’re sure you’ll find the words to win every game.The World’s Most Popular Mobile Word Game now has even more ways to play! Try new rewards and boosts to help you play smarter and faster! ‘car’ – can be made into ‘card, ‘cart’, ‘carp’ etc ‘lush’ – can be made into ‘plush’, blush’, ‘flush’ etc ‘line’ – can be made into ‘incline’, ‘headline’, ‘online’ etc ‘cat’ – can be made into ‘vacate’, ‘catfish’, ‘categorize’ etc And many more… ![]() ED, -ER, -ING, -LY, -ENT, -IEST, -FUL, -ITY, -NESS, -CY, -AL, -TION, -ITEĪ great tactic for winning all three word games is to be on the hunt for easy targets – words that you can add one letter to, gaining you extra points in Scrabble and Words with Friends and saving valuable time in Bananagrams. Second, it allows you to spot opportunities to hijack your opponent’s words, giving you more points! Here are the most common prefixes and suffixes to run through:
![]() Whether you choose all butter, or a 50/50 blend both options can still be delicious! In this recipe, you can substitute up to 50% shortening for the butter. Especially when I did wedding cakes for the bakery, I always incorporated at least some shortening for stability.īut it's just always good to think about whether your particular recipe would benefit from 100% butter or if swapping in some shortening makes more sense for you. Can I use shortening in this buttercream recipe?Ībsolutely! Just because I wouldn't consider it a "buttercream" once there's shortening in there, that is not to say there is anything wrong with using shortening. I like to reserve the term "buttercream" for a frostings that contains 100% butterfat, without any shortening, margarine, etc. Well, this is my own personal definition, but once shortening comes into play, which is common in American buttercream recipes (whether for flavor balance or stability), I would call that particular recipe a "frosting". So when is a "frosting" not a "buttercream"? (Even in this recipes where "easy vanilla buttercream frosting" uses both.) However, while I would call all buttercreams "frosting," I would not call all frostings "buttercreams." What is the difference between frosting and buttercream?įor the most part, I think this difference comes down to naming conventions in a lot of cases. English Buttercream: powdered sugar and butter whipped together (no liquid).American Buttercream: powdered sugar and butter whipped together with a little milk or cream.Which are the quick-mix buttercream frostings? (without eggs) French Buttercream: cooked sugar syrup (water + sugar) is slowly poured into raw whipping egg yolks to cook them right in the mixer bowl, with butter added in slowly at the end.Swiss Buttercream: egg whites and sugar are whisked over a double boiler to dissolve the sugar and cook the eggs then they are whipped on a mixer, with butter slowly added in at the end.Italian Buttercream: cooked sugar syrup (water + sugar) is slowly poured into raw whipping egg whites to cook them right in the mixer bowl, with butter added in slowly at the end. ![]() What are the three classic buttercream frostings? (with eggs) But here's a quick overview of buttercream breakdowns… There are five types of buttercream that I've had experience with during all my years in the kitchen and some are more common and well-defined than others. ![]() So even after my many years making the more official "buttercreams" that my French chef instructors would consider proper buttercreams - Italian Buttercream, Swiss Buttercream, and French Buttercream - the nostalgic notes in this easy vanilla frosting always makes it extra tasty in my book. This is the buttercream I grew up with that my mom always made for our most quintessential family recipe - decorated sugar cookies (I'll be posting this recipe soon too!). Other recipes that fans of this Easy Vanilla Buttercream Frosting will love…Īmerican buttercream is the best buttercream in my book, because it's super easy to make compared to say a Swiss or Italian buttercream and soooo delicious.Can you make other flavors of frosting with this recipe?.Top tip for making the best vanilla frosting….Can you make this recipe ahead of time?.How to make this easy vanilla buttercream from scratch….What tools you'll need to make buttercream….What ingredients you'll need to make this easy buttercream….Can I use shortening in this buttercream recipe?.What is the difference between frosting and buttercream?.It's a breeze to whip up, and can be used to frost cakes, swirl on cupcakes, decorate your favorite sugar cookies, or fill up your macaron shells or whoopie pie sandwiches - the possibilities are endless! Jump to (scroll for more!): Which was GORGEOUS by the way! If you’re interested, this is the one I ordered.Īs for the frosting, I made this one (and dyed it pink).This recipe is the most delightfully light and fluffy.and did we mention.easy vanilla buttercream frosting. I was able to provide the pink frosting just fine, but after realizing my construction efforts are pretty subpar, I turned to Etsy for a ballerina cake topper. Our princess’s request for her birthday cake was a “pink cake with a ballerina on top.” I sure wish time would slow down with these babies of mine. When people say “the days are long but the years are short,” that is the absolute truth. But in reality, it was actually FOUR years ago!!! It seems like just yesterday I was sharing a tutorial on how to make her 1st birthday smash cake. We celebrated our daughter’s fifth birthday last week and even as I type this, I find myself still sitting here in a state of denial! It pipes beautifully, and is the perfect way to finish off all of your cakes and cupcakes! This is The Best Vanilla Buttercream Frosting! It’s rich and creamy, and is super easy to whip up. ![]() In speaking with the President of the HOA, he assured me there was no way this property was ever approved for FHA/HUD financing, nor would it ever be. ![]() My Mother is now 86 years old and should I survive her, I will be forced to live on the streets, homeless and ill. I have since been diagnosed with terminal Cancer for which I am receiving treatment. I am one of the daughters who has resided with my Mother since the passing of my Father in 2013 and subsidizing her loss of his SSA benefits at that time, to date. In fact, there was no mention of their surviving children mentioned anywhere within the contract stating that upon the death of the surviving spouse, the property shall be relinquished to the bank and any tenants residing within the residence will have 30 days to vacate the property. I have read the contract originating from Financial Freedom, which is quite disturbing, in that there are no provisions for the property to go to any beneficiary such as my Sister or myself. I am in desperate need of obtaining documentation treating to a Reverse Mortgage my parents opted to take advantage of in 2006. I am not accepting this answer from Fairway. ![]() is telling me I must make the beneficiaries owners. I have a trustee and myself and my sister listed privately as beneficiaries. after four or five months now Fairway is stating that I cannot have beneficiaries to my Trust. Received months ago, the six-month certificate that I completed the course about being told all about the Reverse Mortgages. Went through the now telephone information study from the state agency that provides pro and con information about the Reverse Mortgage Programs. Another question: I am now trying to deal with a Reverse Mortgage Company called Fairway in Massachusetts. It was stated that amount was never meant to be refunded even if the property was sold. I asked for this amount to be paid back to myself and I was denied. * There was almost a five thousand dollar hold back for some sort of servicing. I ended up selling the property and the proceeds after paying what was due was returned to me. Some five years ago I had a Financial Freedom Reverse Mortgage and things seemed to be fine. “The wholesale reverse mortgage origination channel represents the majority of Financial Freedom’s origination business and is the only wholesale origination channel within OneWest.” “After careful consideration, we have decided to exit the wholesale reverse mortgage origination business based on the regulatory environment and the desire to focus on the bank’s core businesses,” wrote CEO Michelle Minier in a letter to the company’s business partners. Shortly thereafter, in 2011, the company announced it would be shutting down all reverse mortgage channels, citing the regulatory environment and a need to focus on OneWest bank’s “core” operations. The company’s reverse mortgage volume fell substantially after 2007, though it was still the top wholesale lender in 2009. The Federal Reserve publishes CMT yields.Why did Financial Freedom stop offering reverse mortgages?įinancial Freedom has a slightly different story given its change in ownership and the downfall of its parent company, IndyMac, following the market crash of 2007 and subsequent housing market decline. CMT yields are read directly from the Treasury’s daily yield curve, derived from actual yields on Treasury Securities.īecause Treasury instruments have a set maturity date and are issued according to need, it is very rare for the maturity of Treasury security to align with an exact period, e.g., Twelve Months, so interpolation ( weighted averaging) is used to determine the Constant Maturity yields. Treasury (CMT) – Constant Maturity TreasuryĬMT rates are designed to reflect the United States Treasury’s cost of borrowing. By its very definition, SOFR is an overnight rate, so creating longer-term SOFR rates has proved problematic. The US Federal Reserve’s Alternative Reference Rates Committee (ARRC) selected SOFR as the replacement for LIBOR in June 2017. It is derived from actual activity in the Treasuries repurchase (Repo) market, where banks and investors borrow or loan Treasury securities – hundreds of billions of dollars are traded daily. ![]() This methodology allowed for manipulation of the LIBOR rates by large financial institutions, and as a result, regulators have mandated the phase-out of LIBOR.Īs the name indicates, this measures the cost of borrowing cash overnight, secured by Treasuries as collateral. They were not necessarily based on actual transactions. LIBOR rates were determined by a survey of panel banks conducted by the British Bankers Association. There are different LIBOR rates for different borrowing periods and different currencies. This is a measure of the cost to Banks of borrowing cash from each other for relatively short periods. ![]() We can also order a fresh whole pig or lamb, and goats for your next party. The store has regular customers who have been coming in practically since it opened its doors almost 30 years ago.įor home delivery, please call us at 81 for more information. Harmony Farms sells to health food stores, markets and restaurants as well as making home deliveries as far away as Orange County. Buffalo and venison come in many shapes and forms, ready to be simmered into a stew. Also for sale are elk medallions, ostrich meat, wild boar sausage and hunks of Cajun alligator, whole rabbits and duck. Here you can buy hormone-free beef, free-range turkey, lamb and chicken. Harmony Farms is a meat store, a specialty meat store. And during the last week, as pickets kept strike-supporting customers out of the nearby Ralphs and Vons, it was a smell that many people were experiencing once again. Real meat, bloody meat, the kind we used to buy in butcher shops from men in crimson-splashed aprons before the chains took over and put so much cellophane and Styrofoam all over everything it’s hard to tell what it is, exactly. We handle physical, mental & emotional disabilities. So it’s quite a shock to step across the threshold and smell meat. In 1992, I founded Harmony Farms, Inc., an Equine Assisted Therapy Program for individuals with disabilities. From the street, at 40 mph, Harmony Farms could be a granolabinned health food store or an organic fruit stand. Within its immediate vicinity are an escrow company, a florist, a Goodwill donations center, a carwash and a bar called, whimsically enough, Up Th’ Hill. Harmony Farms is a small nondescript storefront on the endless commercial stretch that is Foothill Boulevard in La Crescenta. Harmony Farms is a small nondescript storefront We are a family owned and operated company where everyone truly cares about you, our customers. For more than thirty years we have been providing health conscious consumers like you the very best in all natural meats, poultry, and wild game. Please find more information on their CSA and growing season on the farm individual websites.At Harmony Farms we have been in business since 1972 providing high quality meats and service.
These characters are greatly overshadowed by everyone else in their role. Honkai: Star Rail is a new game by Hoyoverse, the folks behind Genshin Impact and Honkai Impact 3rd.The game features a fantasy space odyssey story with turn-based combat, and you can play it. These characters require a ton of investment to make them viable in harder content.Ĭharacters with limited combat utility. They are considered the base standard of a good character.Ĭharacters who are below average in their respective role. Good characters who can perform even better when given the right amount of investment. Most of these characters offer unique mechanics or have strong Traces that make them better than the rest. ![]() These characters are must-haves and will greatly make your gameplay experience easier.Ĭharacters that are very strong in their respective roles. How often they can activate their abilities while still generating SP. How much a character increases the total DPS output of a team. They all have their own niche and at best share characters/design and lore. Gameplay is fundamentally different from Honkai Impact 3rd or Genshin. How much total damage they can do against 2-3 enemies over a certain number of turns. Star Rail is releasing on the same platform as Genshin Impact and is given the same kind of treatment when it come to localization and VAs. How much Single-Target damage they can do over a certain number of turns. How reliant they are on having specific characters in their team comp. How much damage they can do with their ideal build. DPS units have a slight bias towards Single-Target damage since endgame content will require you to fight against at least one high HP enemy. According to Sensor Tower, Honkai Star Rail made 58,000,000 in June 2023, while Genshin Impact apparently reeled in 32,000,000 that month. Story wise, I'm not sure if you are familiar with what I'm going to mention, but it is probably going to be like Nier Automata to Nier Gestalt/Replicant. 3rd is an action rpg and Rails is a turn based rpg. We rank characters based on our own point based system. 10 3 comments Best Add a Comment DayneAbraxas 2 yr. Tier List Explanation How Characters are Evaluated Added Luocha to the Tier List at SS tier in the Support Category. Recalibrated character rankings based on a new evaluation criteria. Comments (Image credit: MiHoYo) MiHoYo, the developer of gacha powerhouse/memetic virus Genshin Impact, has. Until such a day, all we can do is dream of such a crossover event.- Added Blade to the Tier list with an overall rating at S tier, Single-Target DPS at S tier, and AoE DPS at SS tier. published 7 October 2021 MiHoYo is taking a train back to the Honkai universe. Players speculated the character who would have the most chances of making it into the game would be Fischl due to her lore, as she comes from another universe she was exiled from and would be pretty easy to fit into the title. Obviously, while we would love to see these concepts become a reality, we know there’s actually an extremely low chance it happens in the future. Effects are enhanced if Ushi is still on the field. Itto applies a Resistance debuff to enemies hit and gains Speed.
![]() of 27ħ Comparison Settings provides powerful settings and allows you to find: Duplicates Files - searches for absolutely identical files. Hint: The Photo List can be stored between sessions, so you re able to quit any time and return to the program starting with the same photos. To fast empty the Photo List click Clear List on the toolbar. To remove photos from the Photo List select them in the browser and use the menu Photos > Remove Photos from List or press Command+Delete. If a library is being changed while is launched, close a native application and press the refresh button on the Media Browser window. from Aperture from iphoto from a hard drive (a file) Warning: Close Photos, iphoto, Aperture, Lightroom and Capture One applications before using in order to synchronize library content. of 27Ħ In the browser photos from libraries are indicated with a green ribbon at the top-left corner. Toolbar Add a library, remove the selected or reload content of all libraries. Drag and drop a library file from Finder to this area to add a library. Libraries & Photos Shows all added libraries. Drag and drop photos you want to compare from the Media Browser window to the browser. At the first launch you may need to add your library files to the Media Browser window by using the + button. The Media Browser window appears with previously added libraries, their albums and photos. of 27ĥ To add photos from Photos, iphoto, Aperture, Lightroom or Capture One click Media Browser on the toolbar. All photos inside a folder will be found and added. To add photos from your hard drive drag and drop a folder with your photos from Finder into the browser or press Command+O to show the standard Open panel. The job is done! of 27Ĥ Adding photos You can add photos from your Mac and Photos, iphoto, Aperture, Lightroom and Capture One libraries. Result: A progress window appears and after finishing photos from the hard drive go to the system trash and those from Photos libraries - to the Trash () album. Remove marked photos Click Trash Marked on the toolbar and confirm removal. Result: similar or duplicate photos are marked, but they are still on your hard drive. Mark photos Click Auto Mark on the toolbar, review the marked photos. Result: A progress window appears and after finishing switches to Results mode where you can see duplicate photos in groups. Adjust Time Gap and Matching Level to your needs. Compare photos Click Compare button and select Similar Photos mode. Result: photos from your Photos library are added to the Photo List and shown with a green ribbon. ![]() Add photos from a Photos library: click Media Browser on the Toolbar, add your library and drag and drop photos from the Media window to the browser. Result: photos from your hard drive are added to the Photo List and displayed in the browser. Add your photos Drag and drop a folder with your photos from Finder to the browser. of 27ģ Steps to eliminate duplicate or similar photos 1. Toolbar Provides quick access to the most commonly used functions. Info panel Preview, histogram and metadata. * Compatible with: Photos 1.x iphoto 9.x (ilife '11), 8.x (ilife '09) and 7.x (ilife '08) Aperture 3.x Adobe Lightroom 5.x, 4.x and 3.x Capture One 8.x of 27Ģ Getting Started uses just one screen for all operations and makes all necessary information accessible from the single place. We would like to thank all users who have helped in the further development of by sending us information and bug reports. If you have questions about or seek solutions, it is the best to contact us by We are always eager to hear about any requests and suggestions. Hint: If you re annoyed at a huge number of photos or removing similar photos takes a lot of your time, is a tool you need. It works with photos from Apple Photos, iphoto, Aperture, Adobe Lightroom and Capture One* libraries, as well as photos from your hard drives. 1 Introduction Welcome to Do you really need all 12 shots of that coffee table? helps you organize your photo collections by finding and grouping duplicate or similar photos using powerful comparison settings. ![]() ![]() As a result, a reversible process can change direction at any time, whereas an irreversible process cannot. In contrast, an irreversible process is one in which the intermediate states are not equilibrium states, so change occurs spontaneously in only one direction. In a reversible process, every intermediate state between the extremes is an equilibrium state, regardless of the direction of the change. ![]() Before discussing how to do so, however, we must understand the difference between a reversible process and an irreversible one. The general expression for entropy change. If ∆S is negative, then the negative signs (from the subtraction and the sign of ∆S) will cancel out, and so as T∆S gets bigger, ∆G will get more positive.\) and pronounce “q-reversible”) have unique values for any given process and are therefore state functions.Ĭhanges in entropy (\(ΔS\)), together with changes in enthalpy (\(ΔH\)), enable us to predict in which direction a chemical or physical change will occur spontaneously. Thus, the entropy change is inversely proportional to the temperature of the system. Category: Science & Tech Key People: Cdric Villani Related Topics: second law of thermodynamics chaos theory work energy system See all related content entropy, the measure of a system’s thermal energy per unit temperature that is unavailable for doing useful work. T is always positive, so if ∆S is positive then a bigger T∆S will make ∆G more negative (since we subtract T∆S). The temperature in this equation must be. Solution : Using the results of the solution of the previous problem, one nds SBC CP ln V2 V1. Using this equation it is possible to measure entropy changes using a calorimeter. As T increases, the T∆S component gets bigger. 2 Entropy change in the isobaric-isochoric-isothermic cycle of an ideal gas Show that the entropy change in the cyclic process of an ideal gas that include an isobar, an isochor, and an isotherm is zero. ∆H is still positive and ∆S is still whatever sign you figured out above. Since ∆H and ∆S don't change significantly with temperature (given in the question), we can assume that they keep the same signs and values: i.e. The entropy of a system is related to its energy and temperature, as stated by the equation S Q/T, where S is the change in entropy, Q is the heat added. If ∆G is negative (from the question), is the reaction spontaneous or non-spontaneous?Ģ) Let's use ∆G = ∆H - T∆S again. From these values, we can know for certain whether ∆S is positive or negative (hint: remember that we are subtracting ∆G!).ġ) Knowing the sign of ∆G is enough to say whether the reaction is spontaneous or not under these conditions. Temperature is always positive (in Kelvin). We know (from the question) that ∆G is negative and that ∆H is positive. Three laws govern the science of thermodynamics and here we will discuss the second law of thermodynamics. It also deals with the work done for the conversion of energy from one form to another. The starting point is form (a) of the combined first and second law, For an ideal gas. This looks like a homework question, so I'll give you some hints to get you on the riht path rather than answering directly.ģ) We know that ∆G = ∆H - T∆S. What is Thermodynamics Thermodynamics is the study of the changes in energy associated with the change in temperature and heat. Many aerospace applications involve flow of gases (e.g., air) and we thus examine the entropy relations for ideal gas behavior. |
AuthorWrite something about yourself. No need to be fancy, just an overview. ArchivesCategories |